Vol 23, No 1 (2019) > Mini Conference >

Molecularly Conductive Behavior of Blended Polymer Electrolyte-based CMC/PVA

Noor Saadiah Mohd Ali 1 , Dishen Zhang 2 , Yuki Nagao 2 , Ahmad Salihin Samsudin 3

Affiliations:

  1. Department of Chemistry, Center for Foundation Studies, International Islamic University Malaysia, 26300 Gambang, Pahang
  2. School of Materials Science, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Nomi, Ishikawa 923-1292, Japan
  3. Ionic Materials Team, Faculty of Industrial Sciences & Technology, University Malaysia Pahang, Lebuhraya Tun Razak, 26300, Kuantan, Pahang

 

Abstract: This study investigated the electrical
conduction and structural behavior of blended polymer electrolyte (BPE)-based
carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) in the development of
solid-state electrochemical devices. Based on impedance spectroscopy and
correlating Fourier transform infrared (FTIR) with thermogravimetric analysis,
a framework was proposed to explain the structural enhancement of the BPE
system. As revealed by FTIR, the optimum conductivity of CMC/PVA BPEs was 9.21
× 10−6 Scm−1 for 80:20 composition attributed to the intermolecular attraction
between the polymers. Thermal stability of the CMC/PVA was influenced by the
formation of a hydrogen bond between the hydroxyl (-OH), carboxylate (-COO-), and ether linkage (-COC-) functional groups. The finding provides insights into blended polymer electrolyte-based CMC/PVA, which is beneficial in designing
safe, thin, and lightweight energy storage devices.
Keywords: blended polymer electrolytes, carboxyl methylcellulose, ionic conductivity, structural studies
Published at: Vol 23, No 1 (2019) pages: 27-31
DOI:

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